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Development of SiC-FET methanol sensor

机译:siC-FET甲醇传感器的研制

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摘要

A silicon carbide based field effect transistor (SiC-FET) structure was used for methanol sensing. Due to the chemical stability and wide band gap of SiC, these sensors are suitable for applications over a wide temperature range. Two different catalytic metals, Pt and Ir, were tested as gate contacts for detection of methanol. The sensing properties of both Ir gate and Pt gate SiC-FET sensors were investigated in the concentration range 0.3–5% of methanol in air and in the temperature range 150–350 °C. It was observed that compared to the Ir gate sensor, the Pt gate sensor showed higher sensitivity, faster response and recovery to methanol vapour at comparatively lower temperature, with an optimum around 200 °C. Quantum-chemical calculations were used to investigate the MeOH adsorption and to rationalize the observed non-Langmuir behavior of the response functions. The methanol sensing mechanism of the SiC-FET is discussed.
机译:基于碳化硅的场效应晶体管(SiC-FET)结构用于甲醇感测。由于SiC的化学稳定性和宽带隙,这些传感器适合在宽温度范围内使用。测试了两种不同的催化金属,Pt和Ir,作为用于检测甲醇的栅极触点。 Ir栅极和Pt栅极SiC-FET传感器的感测特性均在空气中甲醇浓度范围为0.3%至5%和150-350°C的温度范围内进行了研究。据观察,与Ir栅极传感器相比,Pt栅极传感器在相对较低的温度下显示出更高的灵敏度,更快的响应和对甲醇蒸气的回收,最佳温度约为200°C。量子化学计算用于研究MeOH吸附并合理化所观察到的响应函数的非朗格缪尔行为。讨论了SiC-FET的甲醇传感机理。

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